Diamond detectors

Science News,  March 1, 2008  by Davide Castelvecchi

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Diamond impurities can detect extremely weak magnetic fields. Probes with diamond tips might soon become sensitive enough to track single atomic nuclei in molecules by their magnetism, enabling the observation of atoms' motion during chemical reactions.

Diamond is an all-carbon crystal, consisting mostly of non-magnetic carbon-12. The nuclei of the relatively rare carbon-13, however, are magnetic. Harvard University physicist Mikhail Lukin and his collaborators used the carbon-13 sandth of the Earth's magnetic field.

Because the orientation of a single carbon-13 nucleus is hard to measure directly, the team devised an approach that takes nuclear magnetic resonance (NMR) down to the atomic level.

All diamonds have impurities, such as a nitrogen atom replacing a carbon in the crystal lattice, or voids where carbon atoms would otherwise be. If a nitrogen atom happens to be right next to a void, its electrons' orbits will expand into the void. As a result, these electrons will show a signature response to light. Nitrogen-vacancy pairs are also few and far between, so the states of such electrons can be manipulated individually using a laser.

The alignment of carbon-13 nuclei will also affect that of the nitrogen-vacancy electrons. Thus, as the carbon-13 nuclei align to an external magnetic field, the nitrogen electrons also respond, a difference detectable with a laser. Lukin and his collaborators could thus take magnetic readings using single nitrogen-vacancy pairs.

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